Paul Wesley and Natalie Kuckenberg looked loved-up as they stepped out in NYC on Sunday - after his ex-wife Ines de Ramon moved on with Brad Pitt.

The Vampire Diaries actor, 40, held hands with the stunning model, 22, as they left a gym in the Big Apple, while wearing matching black ensembles.

Paul wore a black, tee, padded jacket and joggers, teamed with a fawn baseball cap as he chatted.

Natalie wore a chic fitted jacket, slacks, and trainers, while showing off her radiant make-up free complexion.

Before he began seeing his current partner, Wesley was married to his first wife, Torrey DeVitto. 

The former couple initially met while working on the set of the 2007 movie Killer Movie, in which they starred.

The pair tied the knot in 2011, although they went on to divorce two years later.

The actor went on to begin a relationship with Phoebe Tonkin that ended in 2017.

Wesley later began seeing Ines de Ramon, and the former couple surprised many when it was announced that they had married in 2019.

The pair remained together for several years before it was announced that they had separated this past September. 

A representative for the two spoke to People and confirmed that they had been living apart for five months. 

'The decision to separate is mutual and occurred five months ago. They request privacy at this time,' they said.

Wesley later began dating Kuckenburg, and the two were first seen in each other's company just before the announcement about his separation from de Ramon was made. 

Meanwhile Ines, 29, was seen getting up close with Brad, 59, at a Bono concert in November  in exclusive DailyMail.com photos, wore her tresses in soft waves and sported shimmering jewelry as she embraced  Brad before the pair laughed out loud.

Days before the pair were seen packing on the PDA at the LA afterparty for his new film Babylon.

The pair mingled with guests, 'occasionally' with their arms around one another, reports People.

The pair are said to have been dating 'for a few months' with source telling the publication: 'Brad is really into Ines. They met through a mutual friend. She is very nice.

'Ines is cute, fun and energetic. She has a great personality. Brad enjoys spending time with her.

Bachelor Brad, dressed casually in jeans, a gray cardigan and tan hat, has been romantically linked to several women since his tumultuous divorce from Angelina Jolie, but is not usually given to public displays of affection.

Not only do Brad and Ines appear to be an item, but sources tell DailyMail.com that she is a member of his team.

Ines was also in attendance at Brad's 59th birthday party in December, with the pair looking close. 

Although Wesley appeared to be enjoying his time with Kuckenburg, he is also focused on portraying Captain James T. Kirk on Star Trek: Strange New Worlds.

The performer first appeared as the character, who was previously portrayed by William Shatner and Chris Pine, during the final episode of the show's first season.

The actor is set to reprise his role during the program's upcoming second run of episodes.